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Analysis - Starmie

Defensive Combinations

Starmie, as a Water/Psychic type, resists common attacking types of Fighting, Water, Fire, and Ice; it also resists Steel and Psychic, which are not as common attacking types. However, it has a plethora of weaknesses - Electric, Grass, Dark, Ghost, and Bug. The only Pokemon to resist all of Starmie's weaknesses is Magnezone; however, it has a 4x weakness to Ground, and Starmie cannot switch into powerful Ground attacks. Heatran resists all of these types except for Electric, so a Ground type is also recommended in a defensive core consisting of these two. There are no common weaknesses between Starmie and Garchomp, but Grass, Dark, Ghost, and Bug attacks will break down the combination, so a Pokemon like Skarmory is a great complement to those two.

Starmie can use its resistances to benefit Pokemon such as Gliscor (weak to Water and Ice), Heracross and Breloom (weak to Psychic and Fire), Scizor and Levitate Bronzong (weak only to Fire), and Normal types such as Blissey and Porgon-Z (weak to Fighting.) In addition to this, since most of the super-effective attacks used against Starmie will be special (Grass Knot, Thunderbolt, Shadow Ball, Dark Pulse, etc.), Blissey will serve as a decent complement; Gliscor then serves as the finish to a defensive trio, resisting Fighting attacks and taking little from Tyranitar's Crunch.

The easiest way of getting Starmie into battle is against weak attackers, as even though Starmie will run defensive EVs, it will not be able to keep up reliably against the heaviest of hitters. It can switch in relatively easily against Skarmory and Blissey. It will not be threatened by Blissey's Thunder Wave or Toxic, as with the Natural Cure ability, Starmie can switch out to restore status. If Skarmory sets up Spikes or Stealth Rock, Starmie will usually run Rapid Spin to blow them away. Starmie also can switch in relatively easily against Spikers or Stealth Rock users such as Swampert, Forretress and Gliscor, and if they set up their own Stealth Rocks, Starmie can spin them away.